BaF2 Scintillator Crystal

A BaF2 scintillator crystal

BaF2 - Barium Fluoride - is a salt compound of barium and fluorine. In crystal form it is optically transparent over a wide range from the UV through to the IR and widely used to fabricate optical components. It is also has a well established scintillator material.

BaF2 Scintillator Crystals Feature:

  • One of the fastest scintillators with a sub-nanosecond decay time
  • Optical emissions in the form of a ‘fast’ and ‘slow’ pulses
  • Good ‘rad hard’ properties (up to 105 rad)
  • Do not glow in the UV
  • An optical output independent of temperature

Issues to be Aware Of:

  • Slightly hygroscopic with long term exposure to moisture affecting the quality of the surface
  • Very sensitive to thermal shock which can cause fracturing

Common Applications:

  • Time-of-Flight measurements
  • Positron lifetime studies
  • Positron Emission Tomography (PET)
  • Discrimination between gamma rays and neutrons
  • Specialist applications in nuclear and high energy physics

Optical Properties

Property Units Value
Wavelength (Max. Emission) nm 310 (Slow)
195/220 (Fast)
Wavelength Range nm 170 - 460
Decay Times ns 630 (Slow)
0.87/0.88 (Fast)
Light Yield photons/keV 10 (Slow)
1.9 (Fast)
Photoelectron Yield % of NaI(Tl) 16 (Slow)
3 (Fast)
Radiation Length cm 2.026
Radiation Length g.cm-2 9.91
Moliere Radius cm 3.117
Optical Transmission µm 0.15 - 12.5
Transmittance % >90 (0.35 - 9µm)
Refractive Index 1.49 (@ 310nm)
Reflection Loss/Surface % 6.8

Mechanical Properties

Property Units Value
Chemical Formula BaF2
Density g/cm³ 4.893
Atomic Number (Effective) 52.2
Crystal Structure Cubic
Lattice Constant nm 0.6196
Melting Point ºC 1386
Thermal Expansion Coeff. C⁻¹ 18.4 x 10-6
Hardness Mho 3
Hygroscopic Slightly
Solubility g/100g H₂O 0.17 (23ºC)